which the hydrogen bubbles forms around
POLARIZATION
the copper plate is called polarization.
Polarization is the defect of a simple cell
caused by the formation of hydrogen
bubbles around the copper plate.
As zinc reacts with sulphuric acid, it
dissolves and exposes hidden impurities of
carbon and iron. These impurities form
small cells called local cells. These local
cells cause the zinc to be used up even when
current is not being supplied. This defect is
called local action.
These hydrogen bubbles form insulation
layer around the copper therefore blocking
the easy flow of current
HOW TO MINIMIZE POLARISATION
polarization can be minimized by adding a
depolarizer, like potassium dichromate and
manganese oxide. The depolarizer donates
oxygen which combines with hydrogen to
form water.
Example 01
When the bulb is connected between the two
plates of the simple cell, the bulb lights up
however, the brightness of the bulb fades
after about a minute. Explain why its
brightness fades.
A good depolarizer should not react with the
electrolyte.
Answers
This is due to polarization of a simple cell
The brightness of the bulb fades because of
the formation of hydrogen bubbles which
forms an insulating layer on the copper
plate, making it difficult for the electrons to
flow. This makes the bulb to dim.
Note
The hydrogen bubbles formed insulate the
copper plate and prevent other positive
hydrogen ions from receiving electrons from
the copper plate to become neutral. This
increases the resistance inside the cell.
THE CELL DEFECTS
Also, hydrogen ions accumulating at the
copper plate repel other Hydrogen ions (This
defect is called Back e.m.f and opposes or
weakens the main e.m.f of the cell).
Cell defects: - is the failure of a simple cell
to function properly due to formation of
hydrogen bubbles on the copper plate or
small local cells on the zinc plate.
Simple cell has two main defects which
cause the current to diminish quickly when
the cell is being used.
LOCAL ACTION
Local action is the process by which a cell is
used up when no external current is flowing.
Two defects of simple cell are:
As zinc reacts with sulphuric acid, it
dissolves and exposes hidden impurities of
carbon and iron. These impurities form
small cells called local cells. These local
(i) Polarization
(ii) Local Action